Securing cation vacancies to enable reversible Mg insertion/extraction in rocksalt oxides

Author:

Kawaguchi Tomoya1ORCID,Yasuda Masaya12,Nemoto Natsumi12,Shimokawa Kohei13ORCID,Li Hongyi1ORCID,Okamoto Norihiko L.1ORCID,Ichitsubo Tetsu1ORCID

Affiliation:

1. Institute for Materials Research, Tohoku University, Sendai, 9808577, Japan

2. Graduate School of Engineering, Tohoku University, Sendai, 9808579, Japan

3. Frontier Research Institute for Interdisciplinary Sciences, Tohoku University, Sendai, 9808578, Japan

Abstract

Introducing and securing cation vacancies in a crystalline structure activates the disordered rocksalt oxide cathodes for rechargeable magnesium batteries. This strategy provides a new opportunity for novel cathode materials.

Funder

Japan Society for the Promotion of Science

Institute for Materials Research, Tohoku University

Publisher

Royal Society of Chemistry (RSC)

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