Mg-rich disordered rocksalt oxide cathodes for Mg-ion batteries

Author:

Quan Yuan1,Ji Dingqiao1,Yuan Yi1,Xu Hang1,Qi Rui1,De Sousa Coutinho Sofia1,Riedel Sibylle2,Zhao-Karger Zhirong2ORCID,Song Lijiang3ORCID,Robertson Alexander W.3,Bruce Peter G.14ORCID,House Robert A.1ORCID

Affiliation:

1. Department of Materials, University of Oxford, Parks Road, UK

2. Helmholtz Institute Ulm (HIU), Albert-Einstein-Allee 11, D-89081 Ulm, Germany

3. Department of Physics, University of Warwick, Coventry CV4 7AL, UK

4. Department of Chemistry, University of Oxford, South Parks Road, UK

Abstract

Mg-rich disordered rocksalt oxides, Mg2TMO3, are examined as cathodes for Mg-ion batteries. Although Mg2+ cannot easily be extracted from these compounds, we show that Mg2+ can be mobile in other cubic close-packed disordered rocksalts, Li2−xMnO2F.

Funder

Royal Academy of Engineering

John Fell Fund, University of Oxford

Henry Royce Institute

Publisher

Royal Society of Chemistry (RSC)

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