The role of the iodine-atom adduct in the synthesis and kinetics of methyl vinyl ketone oxide—a resonance-stabilized Criegee intermediate
Author:
Affiliation:
1. Institute of Atomic and Molecular Sciences
2. Academia Sinica
3. Taipei 10617
4. Taiwan
5. Department of Chemistry
Abstract
The adduct decomposition is the major pathway that forms CH3(C2H3)COO (MVKO) + I via the reaction of CH3(C2H3)CI + O2 for P > 50 Torr. The related kinetics of the adduct and MVKO + SO2 reactions have been studied over 4–700 Torr and 278–319 K.
Funder
Ministry of Science and Technology, Taiwan
Academia Sinica
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP02085K
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