Structure-dependent reactivity of Criegee intermediates studied with spectroscopic methods-Reference-Cited by-同舟云学术

Structure-dependent reactivity of Criegee intermediates studied with spectroscopic methods

Published:2017 Issue:24 Volume:46 Page:7483-7497
ISSN:0306-0012
Container-title:Chemical Society Reviews
language:en
Short-container-title:Chem. Soc. Rev.

Author:

Jr-Min Lin Jim¹²³⁴⁵^ORCID,Chao Wen¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Atomic and Molecular Sciences

2. Academia Sinica

3. Taipei 10617

4. Taiwan

5. Department of Chemistry

Abstract

Criegee intermediates can be prepared by two methods and may play important roles in atmospheric chemistry. Anti-type Criegee intermediates react quickly with water dimer; Syn-type Criegee intermediates may undergo thermal decomposition via intramolecular hydrogen atom tunneling. In addition, the pros and cons of each spectroscopic method in probing Criegee intermediates in kinetic experiments will also be discussed.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CS/C7CS00336F

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