Reactivity of frustrated Lewis pairs with BOC protected diazocarboxylates: FLP capture of diazene-Reference-Cited by-同舟云学术

Reactivity of frustrated Lewis pairs with BOC protected diazocarboxylates: FLP capture of diazene

Published:2023 Issue:41 Volume:59 Page:6191-6194
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Hussain Zahid¹,Luo Yong-An¹,Wu Yile¹^ORCID,Qu Zheng-Wang²^ORCID,Grimme Stefan²^ORCID,Stephan Douglas W.¹³^ORCID

Affiliation:

1. Institute of Drug Discovery Technology, Ningbo University, Ningbo 315211, Zhejiang, China

2. Mulliken Center for Theoretical Chemistry, Clausius Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Beringstrasse 4, 53115 Bonn, Germany

3. Department of Chemistry, University of Toronto, Toronto, 80 St. George Street, Ontario M5S 3H6, Canada

Abstract

Reactions of (tBuO2CN)2 with FLPs inducing loss of CH2CMe2; using strong bases [Hbase]2 [((C6F5)3BO2CN)2] are isolated whereas with weaker bases diazene derivatives are obtained.

Funder

Deutsche Forschungsgemeinschaft

Natural Science Foundation of Ningbo

Ningbo University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC01571H

Reference32 articles.

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