Addition and NN bond cleavage of diazo-compounds by phosphino-phosphenium cations-Reference-Cited by-同舟云学术

Addition and NN bond cleavage of diazo-compounds by phosphino-phosphenium cations

Published:2024 Issue:8 Volume:60 Page:1031-1034
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kim Hyehwang¹^ORCID,Lough Alan¹,Qu Zheng-wang²^ORCID,Grimme Stefan²^ORCID,Stephan Douglas W.¹³^ORCID

Affiliation:

1. Department of Chemistry, University of Toronto, Toronto, 80 St. George Street, Ontario M5S 3H6, Canada

2. Mulliken Center for Theoretical Chemistry, Clausius Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Beringstrasse 4, Bonn 53115, Germany

3. Institute of Drug Discovery Technology, Ningbo University, Ningbo 315211, Zhejiang, China

Abstract

Phosphino-phosphenium cations react as frustrated Lewis pairs adding across the NN bond of (tBuO2CN)2 and effect the cleavage of the NN bond of (RN)2 affording [Ph2P(μ-NR)2PPh2Cl][GaCl4] (R = Ph, C6H4Cl).

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D3CC05728C

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