The impact of Lewis acid variation on reactions with di-<i>tert</i>-butyl diazo diesters-Reference-Cited by-同舟云学术

The impact of Lewis acid variation on reactions with di-tert-butyl diazo diesters

Published:2024 Issue:2 Volume:53 Page:439-443
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bedi Vaibhav¹^ORCID,Mandal Dipendu¹²^ORCID,Hussain Zahid²,Chen Shi-Ming¹^ORCID,Wu Yile²^ORCID,Qu Zheng-Wang³^ORCID,Grimme Stefan³^ORCID,Stephan Douglas W.¹²^ORCID

Affiliation:

1. Department of Chemistry, University of Toronto, 80 St George Street, Toronto, Ontario M5S 3H6, Canada

2. Institute of Drug Discovery Technology, Ningbo University, Ningbo 315211, Zhejiang, China

3. Mulliken Center for Theoretical Chemistry, Clausius Institut für Physikalische und Theoretische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Beringstrasse 4, 53115 Bonn, Germany

Abstract

Reactions of (tBuO2CN)2 with 9-BBN, BF3 and [Et3Si][B(C6F5)4] afford the heterocyclic products (tBuOCO(BBN)CN)21, [tBuNHNH2tBu][BF4] 2 and [tBuN(H)NtBu][B(C6F5)4] 3, respectively. The mechanism for the formation of 2 is probed computationally.

Funder

Natural Sciences and Engineering Research Council of Canada

Natural Science Foundation of Ningbo

Ningbo University

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03506A

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