Synthesis of characteristic polyisoprenes using rationally designed iminopyridyl metal (Fe and Co) precatalysts: investigation of co-catalysts and steric influence on their catalytic activity-Reference-Cited by-同舟云学术

Synthesis of characteristic polyisoprenes using rationally designed iminopyridyl metal (Fe and Co) precatalysts: investigation of co-catalysts and steric influence on their catalytic activity

Published:2020 Issue:19 Volume:44 Page:8076-8084
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Lin Wenhua¹²³⁴⁵,Zhang Liping¹²³⁴,Suo Hongyi⁵⁶⁷⁸⁴^ORCID,Vignesh Arumugam⁵⁶⁷⁸⁴^ORCID,Yousuf Nighat⁹¹⁰¹¹⁴,Hao Xiang⁵⁶⁷⁸⁴,Sun Wen-Hua⁵⁶⁷⁸⁴^ORCID

Affiliation:

1. School of Textiles and Clothing

2. Jiangnan University

3. Wuxi

4. China

5. Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Science

6. Institute of Chemistry

7. Chinese Academy of Sciences

8. Beijing 100190

9. CAS Research/Education Center for Excellence in Molecular Sciences

10. University of Chinese Academy of Sciences

11. Beijing 100049

Abstract

A series of iminopyridyl ligand-based iron and cobalt complexes are utilized as catalysts in isoprene polymerization, in which the microstructure of resultant polyisoprenes was investigated.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ00942C

Reference67 articles.

1. Discrete iron-based complexes: Applications in homogeneous coordination-insertion polymerization catalysis

2. Recent views on the mechanism of diolefin polymerization with transition metal initiator systems