Enhancing isoprene polymerization with high activity and adjustable monomer enchainment using cyclooctyl-fused iminopyridine iron precatalysts

Author:

Yousuf Nighat123,Ma Yanping1ORCID,Mahmood Qaiser2ORCID,Zhang Wenjuan4ORCID,Wang Yizhou13,Saeed Hassan123,Sun Wen-Hua123ORCID

Affiliation:

1. Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

2. Chemistry and Chemical Engineering Guangdong Laboratory, Shantou 515031, China

3. CAS Research/Education Center for Excellence in Molecular Sciences and International School, University of Chinese Academy of Sciences, Beijing 100049, China

4. Beijing Key Laboratory of Clothing Materials R&D and Assessment, School of Materials Science and Engineering, Beijing Institute of Fashion Technology, Beijing 100029, China

Abstract

In this study, a series of structurally rigid cyclooctyl-fused iminopyridine iron complexes, [L2FeCl][FeCl4] and [2L3Fe][Cl][3FeCl4], was synthesized and investigated as precatalysts on activation with MAO for isoprene polymerization.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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