Application of ferrocene-bridged N-heterocyclic carbene stabilised bis-phosphinidenes in Sn(ii) complexation

Author:

Baierl Ramona1,Kostenko Arseni1ORCID,Hanusch Franziska1ORCID,Inoue Shigeyoshi1ORCID

Affiliation:

1. Department of Chemistry, Catalysis Research Center and Institute of Silicon Chemistry, Technische Universität München, Lichtenbergstraße 4, 85748 Garching bei München, Germany

Abstract

Isolation of new bidentate NHCP ligands was achieved by reaction of a bis(dichlorophosphine) with a NHC and subsequent dichlorination. The NHCPs were used in synthesis of stannyliumylidenes, transmetalation, as well as Sn(ii) transfer reaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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