Triphosphiranes as phosphinidene-transfer agents – synthesis of regular and chelating NHC phosphinidene adducts-Reference-Cited by-同舟云学术

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Triphosphiranes as phosphinidene-transfer agents – synthesis of regular and chelating NHC phosphinidene adducts

Published:2023 Issue:43 Volume:52 Page:15747-15756
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Siewert Jan-Erik¹,Schumann André¹,Wellnitz Tim¹²,Dankert Fabian¹³^ORCID,Hering-Junghans Christian¹^ORCID

Affiliation:

1. Leibniz Institut für Katalyse e.V. (LIKAT), A.-Einstein-Str. 29a, 18059 Rostock, Germany

2. Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg Am Hubland, 97074 Würzburg, Germany

3. Departement für Chemie, Biochemie und Pharmazie, Universität Bern Freiestrasse 3, 3012 Bern, Switzerland

Abstract

Triphosphiranes deliver phosphinidene units to NHCs. A comprehensive series of regular NHCPs is presented and phenylene bridged bis(NHCP)s are introduced.

Funder

Klaus Tschira Stiftung

Leibniz-Gemeinschaft

Fonds der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02690F

Reference56 articles.

1. Substituent effects in polarized phosphaalkenes: a theoretical study of aminocarbene–phosphinidene adducts

2. Phosphaalkenes with Inverse Electron Density

3. A stable crystalline carbene

4. Carbene−Pnictinidene Adducts

5. A Carbene•Phosphinidene Adduct: “Phosphaalkene”

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