Carbene insertion into a P–H bond: parent phosphinidene–carbene adducts from PH3 and bis(phosphinidene)mercury complexes-Reference-Cited by-同舟云学术

Carbene insertion into a P–H bond: parent phosphinidene–carbene adducts from PH3 and bis(phosphinidene)mercury complexes

Published:2016 Issue:14 Volume:45 Page:5999-6003
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bispinghoff Mark¹²³⁴,Tondreau Aaron M.¹²³⁴,Grützmacher Hansjörg¹²³⁴,Faradji Charly A.⁵⁶⁷⁸,Pringle Paul G.⁵⁶⁷⁸

Affiliation:

1. Laboratory of Inorganic Chemistry

2. ETH Zürich

3. 8093 Zürich

4. Switzerland

5. School of Chemistry

6. University of Bristol

7. Bristol BS8 1TS

8. UK

Abstract

The insertion of an N-heterocyclic carbene into a P–H bond is the first step in a new synthesis of parent phosphinidene–carbene adducts from PH₃. These adducts are used to generate bis(phosphinidene)mercury(ii) complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT01741F

Reference39 articles.

1. K. B. Dillon , J. F.Mathey and J. F.Nixon, Phosphorus: The Carbon Copy. From Organophosphorus to Phospha-Organic Chemistry, John Wiley & Sons, Chichester, New York, 1998

2. Stable Carbenes

3. G. Bertrand , in Reactive Intermediate Chemistry, John Wiley & Sons, Inc., Hoboken, New Jersey, 2005, pp. 329–373

4. Heterocyclic Carbenes

5. Heterocyclic Carbenes: Synthesis and Coordination Chemistry

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