(Diphenylphosphino)alkylaldehyde affords hydride- or alkyl-[(diphenylphosphino)alkylacyl]rhodium(iii) or (diphenylphosphino)alkylester complexes: theoretical and experimental diastereoselectivity
Author:
Affiliation:
1. Facultad de Química de San Sebastián
2. Universidad del País Vasco (UPV/EHU)
3. 20080 San Sebastián
4. Spain
5. Ikerbasque
6. Departamento de Química Inorgánica
7. Universidad de Granada
8. Granada
Abstract
Diastereoselective synthesis of 1 and 11 as predicted by DFT. 4 and 10 obtained without and lower diastereoselectivity than predicted.
Funder
Euskal Herriko Unibertsitatea
Ministerio de Economía y Competitividad
Ikerbasque, Basque Foundation for Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04929G
Reference88 articles.
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3. The iridium-catalyzed decarbonylation of aldehydes under mild conditions
4. The Mechanism for the Rhodium-Catalyzed Decarbonylation of Aldehydes: A Combined Experimental and Theoretical Study
5. Cobalt Induced Tandem C−H Activation/Decarbonylation of Various Aromatic Aldehydes and Related Benzylic Alcohols Forming Mononuclear Aryl Monocarbonyl Complexes
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