Formation of Irida-β-ketoimines and PCN<sup>amine</sup>-Ir(III) Complexes by Reacting Irida-β-diketones with Aliphatic Diamines: Catalytic Activity in Hydrogen Release by Methanolysis of H<sub>3</sub>N

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Formation of Irida-β-ketoimines and PCN^amine-Ir(III) Complexes by Reacting Irida-β-diketones with Aliphatic Diamines: Catalytic Activity in Hydrogen Release by Methanolysis of H₃N–BH₃

Published:2022-12-01 Issue:23 Volume:41 Page:3654-3663
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Bustos Itxaso¹,Seco Jose M.¹,Rodriguez-Dieguez Antonio²^ORCID,Garralda María A.¹^ORCID,Mendicute-Fierro Claudio¹^ORCID

Affiliation:

1. Department of Applied Chemistry, Faculty of Chemistry, University of The Basque Country UPV/EHU, Paseo Manuel Lardizabal 3, 20018Donostia-San Sebastián, Spain

2. Department of Inorganic Chemistry, Faculty of Science, University of Granada, 18071Granada, Spain

Funder

Ministerio de Econom?a y Competitividad

Eusko Jaurlaritza

Diputaci?n Foral de Gipuzkoa

Euskal Herriko Unibertsitatea

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.2c00451

Reference47 articles.

1. Metalla-Derivatives of β-Diketones

2. The unique chemistry of platina-β-diketones

3. Aldehyde C–H activation with late transition metal organometallic compounds. Formation and reactivity of acyl hydrido complexes

4. How Strong Are Hydrogen Bonds in Metalla-β-diketones?

5. A hydridoirida-β-diketone as an efficient and robust homogeneous catalyst for the hydrolysis of ammonia–borane or amine–borane adducts in air to produce hydrogen

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