The Mechanism for the Rhodium-Catalyzed Decarbonylation of Aldehydes: A Combined Experimental and Theoretical Study
Author:
Affiliation:
1. Center for Sustainable and Green Chemistry, Department of Chemistry, Building 201, Technical University of Denmark, DK-2800 Lyngby, Denmark, and Department of Chemistry, University of Gothenburg, Kemigården 4, SE-412 96 Göteborg, Sweden
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja710270j
Reference59 articles.
1. Density Functional Study of the Oxidative Addition Step in the Carbonylation of Methanol Catalyzed by [M(CO)2I2]- (M = Rh, Ir)
2. Revisiting the Methyl Iodide Oxidative Addition to Rhodium Complexes: A DFT Study of the Activation Parameters
3. On the importance of electronic and steric effects in the migratory CO insertion step of rhodium–diphosphine catalyzed methanol carbonylation
4. DFT-studies of cis- and trans-[Rh(CO)2X2]+ (X=PH3, PF3, PCl3, PBr3, PI3 or P(CH3)3) and oxidative addition of CH3I to them
5. A Theoretical Study of Steric and Electronic Effects in the Rhodium-Catalyzed Carbonylation Reactions
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