Quasi-isotropic SMMs: slow relaxation of the magnetization in polynuclear Cu<sup>II</sup>/Mn<sup>II</sup> complexes-Reference-Cited by-同舟云学术

Quasi-isotropic SMMs: slow relaxation of the magnetization in polynuclear Cu^II/Mn^II complexes

Published:2022 Issue:5 Volume:51 Page:1779-1783
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pilichos Evangelos¹,Bhunia Pradip²,Font-Bardia Mercè³,Ghosh Ashutosh²⁴^ORCID,Mayans Júlia¹^ORCID,Escuer Albert¹^ORCID

Affiliation:

1. Departament de Química Inorgànica i Orgànica, Secció Inorgànica and Institute of Nanoscience and Nanotechnology (IN2UB), Universitat de Barcelona, Martí i Franquès 1-11, Barcelona-08028, Spain

2. Department of Chemistry, University College of Science, University of Calcutta, Kolkata 700009, India

3. Departament de Mineralogia, Cristal lografia i Dipòsits Minerals, Universitat de Barcelona, Martí Franqués s/n, 08028 Barcelona (Spain) and Unitat de Difracció de R-X. Centre Científic i Tecnològic de la Universitat de Barcelona (CCiTUB), Solé i Sabarís 1-3, 08028 Barcelona, Spain

4. Rani Rashmoni Green University, Hooghly 712410, West Bengal, India

Abstract

Induced SMM responses for polynuclear systems derived from isotropic cations have been characterized for three CuII/MnII clusters with several nuclearities and S ground states. Comparison with isotropic SIMs suggests a similar relaxation mechanism.

Funder

University Grants Commission

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT04074J

Reference30 articles.

1. D.Gatteschi , R.Sessoli and J.Villain , Molecular Nanomagnets , Oxford University Press , Oxford , 2006

2. Design of Single-Molecule Magnets: Insufficiency of the Anisotropy Barrier as the Sole Criterion