Field induced slow magnetic relaxation in a linear homotrinuclear manganese heterospin coordination compound with S = 7/2 ground state and intriguing spin density distribution

Author:

Shcherbakov Igor N.1ORCID,Krotkii Ilya I.1,Kazachkova Victoria I.1,Lyubchenko Sergey N.1,Efimov Nikolay N.2,Tsaturyan Arshak A.34ORCID,Lazarenko Vladimir A.5ORCID

Affiliation:

1. Southern Federal University, Chemistry Department, Rostov-On-Don, 344006, Russian Federation

2. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Moscow, 119991, Russian Federation

3. Université Jean Monnet Saint-Etienne, CNRS, Institut d'Optique Graduate School, Laboratoire Hubert Curien UMR 5516, 42023, Saint-Étienne, France

4. Institute of Physical and Organic Chemistry, Southern Federal University, 194/2 Stachka Ave., Rostov-On-Don, 344090, Russia

5. National Research Center “Kurchatov Institute”, Moscow, 123182, Russian Federation

Abstract

First example of field-induced slow magnetization relaxation in the homotrinuclear linear heterospin manganese coordination compound with S = 7/2 ground state, based on the bidentate 3,5-di-tert-butyl-1,2-benzoquinone-1-monooxime ligand is reported.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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