Cu(<scp>ii</scp>)–Ln(<scp>iii</scp>) (Ln = Gd, Tb and Dy) complexes of an unsymmetrical N<sub>2</sub>O<sub>3</sub> donor ligand: field induced SMM behaviour of Cu(<scp>ii</scp>)–Tb(<scp>iii</scp>) complexes-Reference-Cited by-同舟云学术

Cu(ii)–Ln(iii) (Ln = Gd, Tb and Dy) complexes of an unsymmetrical N₂O₃ donor ligand: field induced SMM behaviour of Cu(ii)–Tb(iii) complexes

Published:2024 Issue:21 Volume:53 Page:9171-9182
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bhunia Pradip¹^ORCID,Maity Souvik¹^ORCID,Ghosh Tanmoy Kumar¹^ORCID,Mondal Arpan²^ORCID,Mayans Júlia³^ORCID,Ghosh Ashutosh¹^ORCID

Affiliation:

1. Department of Chemistry, University College of Science, University of Calcutta, 92, A.P.C. Road, Kolkata-700009, India

2. Department of Chemistry, Indian Institute of Science Education and Research Bhopal, Bhopal by-pass road, Bhauri, Bhopal 462066, MP, India

3. Departament de Química Inorgànica I Orgànica, SeccióInorgànica and Institut de Nanosciència and Nanotecnologia (IN2UB), MartíiFranqués 1-11, 08028 Barcelona, Spain

Abstract

Among three rare types of CuII–LnIII (Ln = Gd, Tb, and Dy) complexes of an unsymmetrical N2O3 donor ligand, only the TbIII derivative shows SMM behavior under a dc field. Theoretical calculations explain the magnetic behavior of the complexes.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00304G

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