Synthesis and catalytic activity of palladium complexes bearing N-heterocyclic carbenes (NHCs) and 1,4,7-triaza-9-phosphatricyclo[5.3.2.1]tridecane (CAP) ligands-Reference-Cited by-同舟云学术

Synthesis and catalytic activity of palladium complexes bearing N-heterocyclic carbenes (NHCs) and 1,4,7-triaza-9-phosphatricyclo[5.3.2.1]tridecane (CAP) ligands

Published:2021 Issue:27 Volume:50 Page:9491-9499
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Scattolin Thomas¹²³⁴,Voloshkin Vladislav A.¹²³⁴^ORCID,Martynova Ekaterina¹²³⁴^ORCID,Vanden Broeck Sofie M. P.¹²³⁴^ORCID,Beliš Marek¹²³⁴^ORCID,Cazin Catherine S. J.¹²³⁴^ORCID,Nolan Steven P.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Center for Sustainable Chemistry

2. Ghent University

3. Ghent

4. Belgium

Abstract

Two synthetic approaches to cis-[Pd(CAP)(NHC)Cl₂] are reported. The catalytic performance of these complexes in the Buchwald–Hartwig aryl amination reaction showed the complex bearing IPr to be the most efficient.

Funder

Bijzonder Onderzoeksfonds

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01716K

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1. Anti-cancer palladium complexes: a focus on PdX2L2, palladacycles and related complexes

2. Synthesis and in-depth studies on the anticancer activity of novel palladacyclopentadienyl complexes stabilized by N-Heterocyclic carbene ligands

3. The anticancer activity of an air-stable Pd(i)-NHC (NHC = N-heterocyclic carbene) dimer