Synthesis and catalytic activity of palladium complexes bearing N-heterocyclic carbenes (NHCs) and 1,4,7-triaza-9-phosphatricyclo[5.3.2.1]tridecane (CAP) ligands
Author:
Affiliation:
1. Department of Chemistry and Center for Sustainable Chemistry
2. Ghent University
3. Ghent
4. Belgium
Abstract
Two synthetic approaches to cis-[Pd(CAP)(NHC)Cl2] are reported. The catalytic performance of these complexes in the Buchwald–Hartwig aryl amination reaction showed the complex bearing IPr to be the most efficient.
Funder
Bijzonder Onderzoeksfonds
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT01716K
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