Dual visible and near-infrared luminescence in mononuclear macrocyclic erbium(iii) complexes via ligand and metal centred excitation

Author:

Gil Yolimar1ORCID,de Santana Ricardo Costa2ORCID,de Camargo Andréa Simone Stucchi3ORCID,Merízio Leonnam Gotardo3ORCID,Carreño Patricia Farías1ORCID,Fuentealba Pablo1ORCID,Manzur Jorge1,Spodine Evgenia1ORCID

Affiliation:

1. Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile, Olivos 1007, 8380544, Santiago, Chile

2. Instituto de Física, Universidade Federal de Goiás, Campus Samambaia, 74690-900, Goiânia, GO, Brazil

3. Instituto de Física de São Carlos, Universidade de São Paulo, Avenida Trabalhador São-Carlense, n°400 Parque Arnold Schimidt, CEP, 13566-590, São Carlos, SP, Brazil

Abstract

The optical studies of three macrocyclic ErIII complexes showed visible upconversion and NIR-downshifted emission upon metal centred excitation. Besides, macrocyclic ligands with aliphatic spacers act as antennas to sensitize the ErIII luminescence.

Funder

Fundação de Amparo à Pesquisa do Estado de Goiás

Financiadora de Estudos e Projetos

Centro para el Desarrollo de la Nanociencia y la Nanotecnología

Fundação de Amparo à Pesquisa do Estado de São Paulo

Fondo Nacional de Desarrollo Científico y Tecnológico

Conselho Nacional de Desenvolvimento Científico e Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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