Harnessing ligand design to develop primary and self-calibrated luminescent thermometers with field-induced single ion magnet behaviour in Dy3+ complexes

Author:

Corredoira-Vázquez Julio12ORCID,González-Barreira Cristina1ORCID,García-Deibe Ana M.1ORCID,Sanmartín-Matalobos Jesús13ORCID,Hernández-Rodríguez Miguel A.2ORCID,Brites Carlos D. S.2ORCID,Carlos Luís D.2ORCID,Fondo Matilde1ORCID

Affiliation:

1. Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain

2. Phantom-g, CICECO – Aveiro Institute of Materials, Department of Physics, University of Aveiro, 3810-193 – Aveiro, Portugal

3. Institute of Materials (iMATUS), Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain

Abstract

Magneto-luminescent studies on Dy+3 complexes of N6 macrocycles lead to a unique [Dy(LN6prop)(OAc)2](NO3)·CHCl3 luminescent primary thermometer based on 2 thermally coupled levels, which in addition shows field-induced single ion magnet behaviour.

Funder

European Cooperation in Science and Technology

Xunta de Galicia

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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