Rhodium-catalyzed regioselective hydroaminomethylation of terminal olefins with pyrrole-based tetraphosphorus ligands-Reference-Cited by-同舟云学术

Rhodium-catalyzed regioselective hydroaminomethylation of terminal olefins with pyrrole-based tetraphosphorus ligands

Published:2014 Issue:4 Volume:4 Page:917-921
ISSN:2044-4753
Container-title:Catal. Sci. Technol.
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Liu Guodu¹²³⁴⁵,Li Zhao¹²³,Geng Huiling¹²³⁴⁵,Zhang Xumu⁴⁵⁶

Affiliation:

1. College of Science

2. Northwest A&F University

3. Yangling, China

4. Department of Chemistry and Chemical Biology and Department of Medicinal Chemistry

5. Rutgers, The State University of New Jersey

6. , USA

Abstract

A protocol was developed to prepare linear amines by regioselective hydroaminomethylation of terminal olefins with pyrrole-based tetraphosphorus ligands. The reactivity of the ligand is modulated by the substituent of the biphenylphosphane moiety, with ligand L5 exhibiting the highest reactivity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CY/C3CY01069D

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