Selective and stable tetraphosphite for Rh-catalyzed linear hydroaminomethylation of aliphatic and aromatic terminal olefins-Reference-Cited by-同舟云学术

Selective and stable tetraphosphite for Rh-catalyzed linear hydroaminomethylation of aliphatic and aromatic terminal olefins

Published:2022 Issue:12 Volume:7 Page:2488-2492
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Yan Xin¹,Zhang Runtong¹,Wang Jiang¹,Yu Hongyi²,Wen Jialin³^ORCID,Bai Shao-Tao³^ORCID,Zhang Xumu¹^ORCID

Affiliation:

1. Guangdong Provincial Key Laboratory of Catalysis, Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055, China

2. Homerton College, University of Cambridge, Cambridgeshire, CB2 8PH, UK

3. Academy for Advanced Interdisciplinary Studies, Southern University of Science and Technology, Shenzhen, 518055, China

Abstract

A highly selective and stable tetraphosphite ligand TBTP was reported for Rh-catalyzed linear selective hydroaminomethylation of both aliphatic and aromatic terminal olefins, giving up to 10 000 TON, 99.9% linear amines with isolated yields up to 98.2%.

Funder

National Natural Science Foundation of China

Basic and Applied Basic Research Foundation of Guangdong Province

National Key Research and Development Program of China

Shenzhen Municipal Science and Technology Innovation Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RE/D2RE00400C

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5. Reductive Amination in the Synthesis of Pharmaceuticals

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