Highly active and regioselective hydroaminomethylation of olefins catalyzed by Rh/sulfoxantphos with ZSM-5-Reference-Cited by-同舟云学术

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Highly active and regioselective hydroaminomethylation of olefins catalyzed by Rh/sulfoxantphos with ZSM-5

Published:2024 Issue:35 Volume:60 Page:4667-4670
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yuan Xiaoshuang¹,Zhang Xueqing¹,Zheng Zhaohui¹²,Sun Shuhui³,Jia Xiaofei¹^ORCID,Dong Shuxiang²

Affiliation:

1. Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China

2. Liaoning Sino More New Material Co., Ltd, Panjin, 124000, P. R. China

3. Xianhe Oil Production Plant, SINOPEC, Dongying, 257000, P. R. China

Abstract

Rh/sulfoxantphos-catalyzed hydroaminomethylation has been developed to afford corresponding linear amines with good yields (71–95%) with high regioselectivities (l/b up to 132.4) and excellent catalytic activities (TON of Rh catalyst up to 23 760).

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00663A

Reference42 articles.

1. Amine-based pretreatments for lignocellulose fractionation and lignin valorization: a review

2. Biobased Amines: From Synthesis to Polymers; Present and Future

3. New Strategies for the Transition-Metal Catalyzed Synthesis of Aliphatic Amines

4. Recent advances in the functionalization of saturated cyclic amines

5. Hydroamination: Direct Addition of Amines to Alkenes and Alkynes

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