Controlled intramolecular H-transfer in malonaldehyde in the electronic ground state mediated through the conical intersection of 1nπ* and 1ππ* excited electronic states-Reference-Cited by-同舟云学术

Controlled intramolecular H-transfer in malonaldehyde in the electronic ground state mediated through the conical intersection of 1nπ* and 1ππ* excited electronic states

Published:2019 Issue:36 Volume:21 Page:20018-20030
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Nandipati K. R.¹²³⁴,Kanakati Arun Kumar¹²³⁴,Singh H.⁵⁶³⁴,Mahapatra S.¹²³⁴^ORCID

Affiliation:

1. School of Chemistry

2. University of Hyderabad

3. Hyderabad

4. India

5. Center for Computational Natural Sciences and Bioinformatics

6. IIIT Hyderabad

Abstract

We report photo-isomerization of malonaldehyde in its electronic ground state (S₀), mediated by coupled ¹nπ*(S₁)–¹ππ*(S₂) excited electronic states, accomplished with the aid of optimally designed ultraviolet (UV)-laser pulses.

Funder

University Grants Commission

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP03762D

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