Assessing the environmental benefit of palladium-based single-atom heterogeneous catalysts for Sonogashira coupling-Reference-Cited by-同舟云学术

Assessing the environmental benefit of palladium-based single-atom heterogeneous catalysts for Sonogashira coupling

Published:2022 Issue:18 Volume:24 Page:6879-6888
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Faust Akl D.¹,Poier D.²,D'Angelo S. C.¹^ORCID,Araújo T. P.¹,Tulus V.¹^ORCID,Safonova O. V.³^ORCID,Mitchell S.¹^ORCID,Marti R.²,Guillén-Gosálbez G.¹^ORCID,Pérez-Ramírez J.¹^ORCID

Affiliation:

1. Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 1, 8093 Zurich, Switzerland

2. Institute of Chemical Technology, University of Applied Sciences and Arts of Western Switzerland Fribourg, Boulevard de Pérolles 80, 1700 Fribourg, Switzerland

3. Paul-Scherrer Institute, Forschungsstrasse 111, 5232 Villigen PSI, Switzerland

Abstract

We quantify through life cycle analysis the environmental benefits of replacing homogeneous with heterogeneous palladium catalysts in Sonogashira coupling and demonstrate the potential of single-atom catalysts (SAC) to lower the footprint.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/GC/D2GC01853E

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3. Process Research and Development of a Dihydropyrimidine Dehydrogenase Inactivator: Large-Scale Preparation of Eniluracil Using a Sonogashira Coupling