Sodiation energetics in pore size controlled hard carbons determined <i>via</i> entropy profiling-Reference-Cited by-同舟云学术

Sodiation energetics in pore size controlled hard carbons determined via entropy profiling

Published:2023 Issue:12 Volume:11 Page:6543-6555
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Mercer Michael P.¹²³^ORCID,Nagarathinam Mangayarkarasi²³^ORCID,Gavilán-Arriazu E. Maximiliano⁴⁵^ORCID,Binjrajka Anshika²,Panda Swoyam²,Au Heather⁶^ORCID,Crespo-Ribadeneyra Maria⁶⁷^ORCID,Titirici Maria-Magdalena⁶^ORCID,Leiva Ezequiel P. M.⁴^ORCID,Hoster Harry E.²³⁸^ORCID

Affiliation:

1. Faculty of Mechanical Engineering, Helmut-Schmidt University, Holstenhofweg 85, 22043 Hamburg, Germany

2. Department of Chemistry, Lancaster University, Bailrigg, Lancaster, LA1 4YB, UK

3. The Faraday Institution, Quad One, Harwell Science and Innovation Campus, Didcot, UK

4. Departamento de Química Teórica y Computacional, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, INFIQC, Córdoba, Argentina

5. Facultad de Matemática, Astronomía y Física, IFEG-CONICET, Universidad Nacional de Córdoba, Córdoba, Argentina

6. Department of Chemical Engineering, Imperial College London, London, UK

7. School of Engineering and Materials Science, Queen Mary University of London, Mile End Road, London E1 4NS, UK

8. Department of Mechanical and Process Engineering, University Duisburg-Essen, Lotharstraße 1, 47057 Duisburg, Germany

Abstract

Cell temperature of hard carbons is varied under open circuit conditions (entropy profiling) during sodiation. Features vary with pore size, revealing the nanopore filling onset. Sodium binding energy scales inversely with pore curvature radius.

Funder

Fondo para la Investigación Científica y Tecnológica

Faraday Institution

Consejo Nacional de Investigaciones Científicas y Técnicas

Engineering and Physical Sciences Research Council

Royal Academy of Engineering

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/TA/D2TA09406A