Reactions of co-ordinated ligands. Part 57. Synthesis, structure and interrelationship of 2-σ-butadienyl and cationic (1,2,3-η)-trans-butadienyl-platinum and -palladium complexes; crystal structures of cis-[PtCl{σ-C(CH2)C(Et)CH2}(dppf)] and [Pt{(1,2,3-η)-trans-CH2C(Et)CCH2}(PPh3)2][PF6][dppf = 1,1′-bis(diphenylphosphino)ferrocene]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1993/DT/DT9930003785
Reference22 articles.
1. Reactions of co-ordinated ligands. Part 56. Synthesis and reactivity of [Mo{η3,η3-CH(Me)C(Me)CHCHC(Me)CH2}(Co)(η-C5H5)][BF4] formed by coupling of but-2-yne and isoprene ligands; reactions of [Mo(η2-C2H4)(η2-MeC2Me)(CO)(η-C5H5)][BF4]
2. Reactions of co-ordinated ligands. Part 54. Synthesis of (1,2,3-η)-trans-butadienyl complexes by deprotonation or desilylation of cationic molybdenum 1,3-diene complexes; formation of η4-vinylketene complexes and crystal structures of [Mo{(1,2,3-η)-trans-CH2CHCCH2}(CO)2(η-C5Me5)], [Mo{η3-CH2CC(Me)CH2CO}(CO)2(η-C5Me5)] and [Mol{η4-CH2CHC(Me)CO}(CO)(η-C5Me5)]
3. Synthesis and reactivity of cationic (.eta.3-butadienyl)platinum complexes
4. A novel transition metal-promoted rearrangement of a cyclopropenyl cation. Synthesis and crystal and molecular structure of a 1-3-.eta.-butadienyl complex of platinum
5. The interaction of 1,1,3,3-tetrakis(trifluoromethyl)allene with sodium derivatives of iron and rhenium carbonyl compounds. Synthesis and structure of the σ- and π-complexes
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