Reactions of co-ordinated ligands. Part 54. Synthesis of (1,2,3-η)-trans-butadienyl complexes by deprotonation or desilylation of cationic molybdenum 1,3-diene complexes; formation of η4-vinylketene complexes and crystal structures of [Mo{(1,2,3-η)-trans-CH2CHCCH2}(CO)2(η-C5Me5)], [Mo{η3-CH2CC(Me)CH2CO}(CO)2(η-C5Me5)] and [Mol{η4-CH2CHC(Me)CO}(CO)(η-C5Me5)]
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1992/DT/DT9920003453
Reference41 articles.
1. Reactions of co-ordinated ligands. Part 53. Synthesis of dimolybdenum and ditungsten µ-σ,η2-(4e)-vinylidene and -allenylidene complexes; crystal structures of [N(PPh3)2][Mo2{µ-σ:η2-(3e)-C2Ph}(CO)4(η5-C9H7)2], [Mo2{µ-σ:η2-(4e)-CC(Ph)(CH2)4OMe}(CO)4(η-C5H5)2] and [Mo2{µ-σ:η2-(4e)-CCCMe2}(CO)4(η-C5H5)2]
2. The interaction of 1,1,3,3-tetrakis(trifluoromethyl)allene with sodium derivatives of iron and rhenium carbonyl compounds. Synthesis and structure of the σ- and π-complexes
3. Double addition du methanol sur des complexes η5-cyclopentadienyl η1-hexadiyne-2,4-yl tricarbonyl molybdene et dicarbonyl fer
4. Cyclopentadienyl-ruthenium and -osmium chemistry. Cleavage of tetracyanoethylene under mild conditions: X-ray crystal structures of [Ru{η3-C(CN)2CPhCC(CN)2}(PPh3)(η-C5H5)] and [Ru{C[C(CN)2]CPhC(CN)2}-(CNBut)(PPh3)(η-C5H5)]
5. Reactions between tetracyanoethylene and transition metal acetylides: Formation and cleavage of the cyclobutenyl ring in an authentic tetracyanocyclobutenylmetal complex, W[(CN)2](CO)3(η-C5H5)
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