Reactions of co-ordinated ligands. Part 56. Synthesis and reactivity of [Mo{η3,η3-CH(Me)C(Me)CHCHC(Me)CH2}(Co)(η-C5H5)][BF4] formed by coupling of but-2-yne and isoprene ligands; reactions of [Mo(η2-C2H4)(η2-MeC2Me)(CO)(η-C5H5)][BF4]-Reference-Cited by-同舟云学术

Reactions of co-ordinated ligands. Part 56. Synthesis and reactivity of [Mo{η3,η3-CH(Me)C(Me)CHCHC(Me)CH2}(Co)(η-C5H5)][BF4] formed by coupling of but-2-yne and isoprene ligands; reactions of [Mo(η2-C2H4)(η2-MeC2Me)(CO)(η-C5H5)][BF4]

Published:1993 Issue:11 Volume: Page:1761-1770
ISSN:0300-9246
Container-title:J. Chem. Soc., Dalton Trans.
language:en
Short-container-title:J. Chem. Soc., Dalton Trans.

Author:

Carfagna Carla,Green Michael,Nagle Katherine R.,Williams David J.,Woolhouse Christopher M.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/1993/DT/DT9930001761

Reference32 articles.

1. Part 55, L.Brammer, B. J.Dunne, M.Green, G.Moran, A. G.Orpen, C.Reeve and C. J.Schaverien, preceding paper.

2. Synthesis and reactivity of cationic alkene–alkyne molybdenum complexes; structural evidence for the formation of an η3,η3-bonded hexatriene ligand by coupling of a co-ordinated alkyne and a 1,3-diene

3. Reactions of co-ordinated ligands. Part 28. The reaction of nucleophilic reagents with the cationic bis(acetylene) molybdenum complexes [Mo(CO)(RC2R′)2(η-C5H5)][BF4]; X-ray crystal structures of [Mo{C(Me)C(Me)C(O)C(Me)CHMe}(CO)2(η-C5H5)] and [Mo{η3:η2-HButCCHC–O–C(O)C(But)CH}(CO)(η-C5H5)]

4. Four-Electron Alkyne Ligands in Molybdenum(II) and Tungsten(II) Complexes

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Thiolates vs. halides as π-donors: the redox-active alkyne complexes [M(SR)L(η-R′CCR′)L′] {M = Mo or W, L = CO or P(OMe)3, L′ = η-C5H5 and Tp′};Dalton Transactions;2009

2. The d4/d3redox pairs [MX(CO)(η-RCCR)Tp′]z(z = 0 and 1): structural consequences of electron transfer and implications for the inverse halide order;Dalton Trans.;2007

3. The cis-insertion of diphenylacetylene into an exo-polyhedral boron–hydrogen bond of a molybdenacarbaborane cage;J. Chem. Soc., Chem. Commun.;1995

4. π-Complexes of Chromium, Molybdenum and Tungsten, Excluding those of Cyclopentadienyls and Arenes;Comprehensive Organometallic Chemistry II;1995

5. Reactions of co-ordinated ligands. Part 57. Synthesis, structure and interrelationship of 2-σ-butadienyl and cationic (1,2,3-η)-trans-butadienyl-platinum and -palladium complexes; crystal structures of cis-[PtCl{σ-C(CH2)C(Et)CH2}(dppf)] and [Pt{(1,2,3-η)-trans-CH2C(Et)CCH2}(PPh3)2][PF6][dppf = 1,1′-bis(diphenylphosphino)ferrocene];J. Chem. Soc., Dalton Trans.;1993