The d4/d3redox pairs [MX(CO)(η-RCCR)Tp′]z(z = 0 and 1): structural consequences of electron transfer and implications for the inverse halide order-Reference-Cited by-同舟云学术

The d4/d3redox pairs [MX(CO)(η-RCCR)Tp′]z(z = 0 and 1): structural consequences of electron transfer and implications for the inverse halide order

Published:2007 Issue:1 Volume: Page:62-72
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Adams Christopher J.,Bartlett Ian M.,Carlton Susannah,Connelly Neil G.,Harding David J.,Hayward Owen D.,Orpen A. Guy,Patron Elena,Ray Christopher D.,Rieger Philip H.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2007/DT/B611472E

Reference23 articles.

1. Redox routes to arenechromium complexes of two-, three- and four-electron alkynes; structure and bonding in paramagnetic [Cr(CO)L(η-RCCR)(η-arene)]+

2. Structural consequences of the one-electron reduction of d4[Mo(CO)2(η-PhCCPh)Tp′]+and the electronic structure of the d5radicals [M(CO)L(η-MeCCMe)Tp′] {L = CO and P(OCH2)3CEt}

3. Structure and bonding in the d4/d3 alkyne redox pairs [WX(CO)(MeCCMe)Tp′]z (X = F, Cl, Br and I; z = 0 and 1): halide stabilisation of electron deficient metal alkyne complexes

4. Synthesis and characterization of chiral (hydridotris(3,5-dimethylpyrazolyl)borato)tungsten(II) alkyne complexes

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