Isolation of two bis(silyl)nickel complexes with Si–Si bond formation in a single-crystal-to-single-crystal fashion-Reference-Cited by-同舟云学术

Isolation of two bis(silyl)nickel complexes with Si–Si bond formation in a single-crystal-to-single-crystal fashion

Published:2019 Issue:10 Volume:48 Page:3433-3439
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zhang Sen-Yu¹²³⁴⁵,Li Jie¹²³⁴⁵,Zhao Sheng-Ze¹²³⁴⁵,Wang Shi¹²³⁴⁵^ORCID,Lu Min-Ming¹²³⁴⁵,Li Yong-Hua¹²³⁴⁵^ORCID,Huang Wei¹²³⁴⁵

Affiliation:

1. Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials (IAM)

2. Jiangsu National Synergistic Innovation Center for Advanced Materials (SICAM)

3. Nanjing University of Posts & Telecommunications

4. Nanjing 210023

5. China

Abstract

Two unique silyl nickel complexes that generate two new Si–Si single bonds have been prepared unprecedentedly, which exhibit reversible single-crystal-to-single-crystal transformations upon the removal and rebinding of the coordinating PEt₃ molecule.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Ministry of Education of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04951C

Reference43 articles.

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3. Isolation of a Hydrogen-Bridged Bis(silylene) Tungsten Complex: A Snapshot of a Transition State for 1,3-Hydrogen Migration

4. Pd/C-Catalyzed Hydrosilylation of Enals and Enones with Triethylsilane: Conformer Populations Control the Stereoselectivity

5. Reaction of 1,2-Disilylbenzene with Bis[1,2-bis(dimethylphosphino)ethane]nickel(0). Isolation and Characterization of the First Silylnickel(IV) Complex

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