Trapping of two mononuclear silyl platinum(ii)/palladium(ii) complexes and a unique dinuclear bis(μ2-disilene)(silyl)nickel(ii) complex-Reference-Cited by-同舟云学术

Trapping of two mononuclear silyl platinum(ii)/palladium(ii) complexes and a unique dinuclear bis(μ2-disilene)(silyl)nickel(ii) complex

Published:2020 Issue:46 Volume:44 Page:20351-20357
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Song Hao¹²³⁴⁵,Zhang Sen-Yu⁶⁷³⁴⁵,Gu Peng-Fei⁶⁷³⁴⁵,Wu Hua-Yu⁶⁷³⁴⁵,Wang Zi-Kun⁶⁷³⁴⁵,Wang Shi⁶⁷³⁴⁵^ORCID,Wang Zheng⁸⁹¹⁰¹¹⁵,Gu Yu-Yang⁶⁷³⁴⁵,Li Yong-Hua⁶⁷³⁴⁵^ORCID

Affiliation:

1. New Energy Technology Engineering Lab of Jiangsu Province

2. School of Science

3. Nanjing University of Posts & Telecommunications

4. Nanjing 210023

5. China

6. Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials (IAM)

7. Jiangsu National Synergistic Innovation Center for Advanced Materials (SICAM)

8. College of Chemistry and Chemical Engineering

9. Key Laboratory of Chemical Additives for China National Light Industry

10. Shaanxi University of Science and Technology

11. Xi’an 710021

Abstract

Two rare mononuclear bis(silyl)platinum(ii)/palladium(ii) intermediates and an unprecedented dinuclear bis(μ₂-disilene)(silyl)nickel(ii) complex have been trapped and prepared.

Funder

National Natural Science Foundation of China

Priority Academic Program Development of Jiangsu Higher Education Institutions

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ04079G

Reference31 articles.

1. Reactions of Hydrosilanes with Transition Metal Complexes

2. Isolation of a Hydrogen-Bridged Bis(silylene) Tungsten Complex: A Snapshot of a Transition State for 1,3-Hydrogen Migration

3. Disilene–Silylene Interconversion: A Synthetically Accessible Acyclic Bis(silyl)silylene

4. Square-Planar Iron(II) Silyl Complexes: Synthesis, Characterization, and Insertion Reactivity

5. Pd/C-Catalyzed Hydrosilylation of Enals and Enones with Triethylsilane: Conformer Populations Control the Stereoselectivity