Isolation of a Hydrogen-Bridged Bis(silylene) Tungsten Complex: A Snapshot of a Transition State for 1,3-Hydrogen Migration
Author:
Affiliation:
1. Departmet of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
2. Fukui Institute for Fundamental Chemistry, Kyoto University, Kyoto 603-8103, Japan
Funder
Ministry of Education, Culture, Sports, Science, and Technology
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja512336v
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5. .sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bonds
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