Synthesis, structure and reactivity of NO+, NO˙ and NO− pincer PCN-Rh complexes-Reference-Cited by-同舟云学术

Synthesis, structure and reactivity of NO+, NO˙ and NO− pincer PCN-Rh complexes

Published:2020 Issue:21 Volume:49 Page:7093-7108
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gallego Cecilia Mariel¹²³⁴⁵^ORCID,Gaviglio Carina⁶⁷⁸⁹¹⁰^ORCID,Ben-David Yehoshoa¹¹¹²¹³¹⁴,Milstein David¹¹¹²¹³¹⁴^ORCID,Doctorovich Fabio¹²³⁴⁵^ORCID,Pellegrino Juan¹²³⁴⁵^ORCID

Affiliation:

1. Departamento de Química Inorgánica

2. Analítica

3. y Química Física

4. Facultad de Ciencias Exactas y Naturales

5. Universidad de Buenos Aires

6. Comisión Nacional de Energía Atómica

7. CAC-GIyANN

8. Departamento de Física de la Materia Condensada

9. Buenos Aires

10. Argentina

11. Department of Organic Chemistry

12. The Weizmann Institute of Science

13. Rehovot

14. Israel

Abstract

Synthesis of a rhodium PCN pincer-type nitrosyl complex is described. Coordination to the metallic center by weakly coordinating anions was found, as well as a slight stabilization of higher oxidation states when compared to a PCP analogue.

Funder

Universidad de Buenos Aires

Fondo para la Investigación Científica y Tecnológica

Consejo Nacional de Investigaciones Científicas y Técnicas

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00962H

Reference64 articles.

1. NO News Is Good News