A multi-technique approach to unveil the redox behaviour and potentiality of homoleptic Cu<sup>I</sup> complexes based on substituted bipyridine ligands in oxygenation reactions-Reference-Cited by-同舟云学术

A multi-technique approach to unveil the redox behaviour and potentiality of homoleptic Cu^I complexes based on substituted bipyridine ligands in oxygenation reactions

Published:2022 Issue:38 Volume:51 Page:14439-14451
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Centrella Barbara¹,Deplano Gabriele¹^ORCID,Damin Alessandro¹,Signorile Matteo¹^ORCID,Tortora Mariagrazia²³^ORCID,Barolo Claudia¹⁴^ORCID,Bonomo Matteo¹^ORCID,Bordiga Silvia¹^ORCID

Affiliation:

1. Department of Chemistry and NIS Interdepartmental Center and INSTM reference center, University of Turin, via Pietro Giuria 7, I-10125 Turin, Italy

2. AREA SCIENCE PARK, Padriciano, 99, 34149 Trieste, Italy

3. Elettra-Sincrotrone Trieste, S.S. 114 km 163.5, Basovizza, 34149, Trieste, Italy

4. ICxT Interdepartmental Centre, Università degli Studi di Torino, Lungo Dora Siena 100, 10153 Torino, Italy

Abstract

The reaction of CuI(bpy)2 complexes with tBuOOH was followed by a multi-technique approach (DFT-supported lab-scale or synchrotron spectroscopies and electrochemistry). The findings evidence the formation of a CuIIOH species as reactive intermediate.

Funder

H2020 Environment

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01234K

Reference70 articles.

1. The principles of distribution of chemical elements in minerals and rocks. The seventh Hugo Müller Lecture, delivered before the Chemical Society on March 17th, 1937

2. Copper – Element information, properties and uses | Periodic Table, https://www.rsc.org/periodic-table/element/29/copper

3. U.S. Geological Survay, https://minerals.usgs.gov/minerals/

4. Life Cycle Assessment of Metals: A Scientific Synthesis

5. Dynamic analysis of European copper flows

Cited by 4 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. A Raman lens on the active sites in the oxygenation of cyclohexene catalyzed by a Cu-bipyridine homoleptic complex;Catalysis Today;2024-11

2. Modulation of [CuOH/O]⁺ Properties in [2,2′-Bipyridine]₂ Homoleptic Complexes through Substitution at the 6,6’ Position by Methyl Groups;ACS Omega;2024-03-29

3. Probing the effect of the Si/Al ratio in Cu-CHA zeolite catalysts on SO₂ exposure: in situ DR UV-vis spectroscopy and deactivation measurements;Catalysis Science & Technology;2024

4. Copper and Zinc Complexes of 2,7-Bis(6-methyl-2-pyridyl)-1,8-naphthyridine─A Redox-Active, Dinucleating Bis(bipyridine) Ligand;Inorganic Chemistry;2022-11-21