Tris-(2-pyridylmethyl)amine-ligated Cu(ii) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives-Reference-Cited by-同舟云学术

Tris-(2-pyridylmethyl)amine-ligated Cu(ii) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives

Published:2021 Issue:5 Volume:50 Page:1712-1720
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Elsberg Josiah G. D.¹²³⁴^ORCID,Anderson Stephen N.¹²³⁴^ORCID,Tierney David L.¹⁵⁶⁴^ORCID,Reinheimer Eric W.⁷⁸⁴^ORCID,Berreau Lisa M.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry & Biochemistry

2. Utah State University

3. Logan

4. USA

5. Miami University

6. Oxford

7. Rigaku Americas Corporation

8. The Woodlands

Abstract

Six-coordinate Cu(ii) diketonate complexes were isolated and characterized; TPA-ligated Cu(ii) chlorodiketonate derivatives exhibit anaerobic retro-Claisen reactivity.

Funder

National Science Foundation

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04074F

Reference27 articles.

1. Oxygenation via C–H/C–C Bond Activation with Molecular Oxygen

2. Oxidative aliphatic carbon–carbon bond cleavage reactions