Tris-(2-pyridylmethyl)amine-ligated Cu(ii) 1,3-diketonate complexes: anaerobic retro-Claisen and dehalogenation reactivity of 2-chloro-1,3-diketonate derivatives

Author:

Elsberg Josiah G. D.1234ORCID,Anderson Stephen N.1234ORCID,Tierney David L.1564ORCID,Reinheimer Eric W.784ORCID,Berreau Lisa M.1234ORCID

Affiliation:

1. Department of Chemistry & Biochemistry

2. Utah State University

3. Logan

4. USA

5. Miami University

6. Oxford

7. Rigaku Americas Corporation

8. The Woodlands

Abstract

Six-coordinate Cu(ii) diketonate complexes were isolated and characterized; TPA-ligated Cu(ii) chlorodiketonate derivatives exhibit anaerobic retro-Claisen reactivity.

Funder

National Science Foundation

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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