Light-induced O<sub>2</sub>-dependent aliphatic carbon–carbon (C–C) bond cleavage in bipyridine-ligated Co(<scp>ii</scp>) chlorodiketonate complexes-Reference-Cited by-同舟云学术

Light-induced O₂-dependent aliphatic carbon–carbon (C–C) bond cleavage in bipyridine-ligated Co(ii) chlorodiketonate complexes

Published:2023 Issue:13 Volume:52 Page:4152-4160
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Anderson Stephen N.¹^ORCID,Elsberg Josiah G. D.¹^ORCID,Berreau Lisa M.¹^ORCID

Affiliation:

1. Department of Chemistry & Biochemistry, Utah State University, Logan, UT 84322-0300, USA

Abstract

Illumination of aerobic acetonitrile solutions of bipyridine-ligated Co(ii) chlorodiketonate complexes results in O2-dependent aliphatic C–C bond cleavage with high 18O incorporation.

Funder

National Institute of General Medical Sciences

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03727K

Reference63 articles.

1. Iron-catalyzed oxidative C–C(vinyl) σ-bond cleavage of allylarenes to aryl aldehydes at room temperature with ambient air

2. Iron-catalyzed aerobic oxidative cleavage of the C–C σ-bond using air as the oxidant: chemoselective synthesis of carbon chain-shortened aldehydes, ketones and 1,2-dicarbonyl compounds

3. Novel synthesis of divergent aryl imidazoles from ketones involving copper-catalyzed α-amination and oxidative C–C bond cleavage

4. Copper Catalyzed Oxidative C–C Bond Cleavage of 1,2-Diketones: A Divergent Approach to 1,8-Naphthalimides, Biphenyl-2,2′-dicarboxamides, and N-Heterocyclic Amides

5. New protocol of copper-catalyzed oxidative C(CO) C bond cleavage of aryl and aliphatic ketones to organic acids using O2 as the terminal oxidant

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Anion- and water-facilitated oxidative carbon–carbon bond cleavage and diketonate carboxylation in Cu(II) chlorodiketonate complexes;Inorganica Chimica Acta;2024-10

2. Chelated O₂BOH^2– or Chelated O₂CO^2–: An Isoelectronic Conundrum;Inorganic Chemistry;2023-10-26