Radical anionic versus neutral 2,2′-bipyridyl coordination in uranium complexes supported by amide and ketimide ligands-Reference-Cited by-同舟云学术

Radical anionic versus neutral 2,2′-bipyridyl coordination in uranium complexes supported by amide and ketimide ligands

Published:2015 Issue:6 Volume:44 Page:2676-2683
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Diaconescu Paula L.¹²³⁴,Cummins Christopher C.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Massachusetts Institute of Technology

3. Cambridge

4. USA

Abstract

A series of 2,2′-bipyridyl uranium complexes shows that bipy is found as a radical anion or a neutral ligand such that uranium is in the +4 oxidation state.

Funder

National Science Foundation

David and Lucile Packard Foundation

National Science Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT02422B

Reference52 articles.

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3. Electronic Structures of Tris(2,2′-bipyridyl) Complexes of Transition Metals in Lower Oxidation States

4. Coordination of 2,2‘-Bipyridyl and 1,10-Phenanthroline to Substituted Ytterbocenes: An Experimental Investigation of Spin Coupling in Lanthanide Complexes

5. Decamethylytterbocene Complexes of Bipyridines and Diazabutadienes: Multiconfigurational Ground States and Open-Shell Singlet Formation

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