Assembling diuranium complexes in different states of charge with a bridging redox-active ligand-Reference-Cited by-同舟云学术

Assembling diuranium complexes in different states of charge with a bridging redox-active ligand

Published:2022 Issue:38 Volume:13 Page:11294-11303
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Modder Dieuwertje K.¹,Batov Mikhail S.¹^ORCID,Rajeshkumar Thayalan²,Sienkiewicz Andrzej³⁴^ORCID,Zivkovic Ivica³^ORCID,Scopelliti Rosario¹^ORCID,Maron Laurent²^ORCID,Mazzanti Marinella¹^ORCID

Affiliation:

1. Group of Coordination Chemistry, Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland

2. Laboratoire de Physique et Chimie des Nano-objets, Institut National des Sciences Appliquées, Cedex 4, 31077 Toulouse, France

3. Laboratory for Quantum Magnetism, Institute of Physics, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland

4. ADSresonances Sàrl, Route de Genève 60B, 1028 Préverenges, Switzerland

Abstract

Convenient routes to dinuclear complexes of uranium where two uranium centers are bridged by the redox-active ligand bpym were identified resulting in unique and stable radical-bridged dimetallic complexes of U(iii) and U(iv) showing SMM behaviour.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

École Polytechnique Fédérale de Lausanne

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC03592H

Reference104 articles.

1. Giant coercivity and high magnetic blocking temperatures for N2 3− radical-bridged dilanthanide complexes upon ligand dissociation

2. Molecular magnetic hysteresis at 60 kelvin in dysprosocenium