Nitrogen activation and cleavage by a multimetallic uranium complex-Reference-Cited by-同舟云学术

Nitrogen activation and cleavage by a multimetallic uranium complex

Published:2022 Issue:27 Volume:13 Page:8025-8035
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Keener Megan¹^ORCID,Fadaei-Tirani Farzaneh¹^ORCID,Scopelliti Rosario¹^ORCID,Zivkovic Ivica²,Mazzanti Marinella¹^ORCID

Affiliation:

1. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland

2. Laboratory for Quantum Magnetism, Institute of Physics, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland

Abstract

Combinations of ligands were used to tune UNU complexes yielding a U(iii)/U(iii) nitride, which activates N2. Parallel N2 reduction pathways were identified, leading to the first example of N2 cleavage by U without external alkali reducing agents.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

École Polytechnique Fédérale de Lausanne

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC02997A

Reference84 articles.

1. Recent Advances in Transition Metal-Catalyzed Dinitrogen Activation

2. Nitrogen reduction and functionalization by a multimetallic uranium nitride complex