Metal control of selectivity in acetate-assisted C–H bond activation: an experimental and computational study of heterocyclic, vinylic and phenylic C(sp2)–H bonds at Ir and Rh-Reference-Cited by-同舟云学术

Metal control of selectivity in acetate-assisted C–H bond activation: an experimental and computational study of heterocyclic, vinylic and phenylic C(sp2)–H bonds at Ir and Rh

Published:2014 Issue:6 Volume:5 Page:2340-2346
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Carr Kevin J. T.¹²³,Davies David L.⁴⁵⁶,Macgregor Stuart A.¹²³,Singh Kuldip⁴⁵⁶,Villa-Marcos Barbara⁴⁵⁶

Affiliation:

1. Institute of Chemical Sciences

2. Heriot-Watt University

3. Edinburgh EH14 4AS, UK

4. Department of Chemistry

5. University of Leicester

6. Leicester LE1 7RH, UK

Abstract

Experimental and DFT studies show the selectivity of C–H bond activation at [MCl₂Cp*]₂ (M = Ir, Rh) species can be controlled by the choice of metal catalyst, reflecting kinetic control at M = Ir and thermodynamic control at M = Rh.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C4SC00738G

Reference37 articles.

1. Cyclometalation Using d-Block Transition Metals: Fundamental Aspects and Recent Trends

2. C—H Bond Activation in Transition Metal Species from a Computational Perspective

3. Mechanisms of C–H bond activation: rich synergy between computation and experiment

4. Activation of carbon–hydrogen bonds and dihydrogen by 1,2-CH-addition across metal–heteroatom bonds

5. N−H versus C−H Activation of a Pyrrole Imine at {Cp*Ir}: A Computational and Experimental Study

Cited by 46 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. DLPNO-CCSD(T) and DFT study of the acetate-assisted C–H activation of benzaldimine at [RuCl₂(p-cymene)]₂: the relevance of ligand exchange processes at ruthenium(ii) complexes in polar protic media;Dalton Transactions;2024

2. Rh(III)-Catalyzed C–H Activation/Annulation of Benzohydroxamates and 2-Imidazolones: Access to Urea-Fused-Dihydroisoquinolone Scaffolds Reminiscent of Pyrrole Alkaloid Natural Products;Organic Letters;2022-09-09

3. Manganese-Mediated C–H Bond Activation of Fluorinated Aromatics and the ortho-Fluorine Effect: Kinetic Analysis by In Situ Infrared Spectroscopic Analysis and Time-Resolved Methods;ACS Catalysis;2022-01-11

4. Reduction of Np(vi) with hydrazinopropionitrile via water-mediated proton transfer;Physical Chemistry Chemical Physics;2022

5. Experimental and Computational Studies on the Acetate-Assisted C–H Activation of N-Aryl Imidazolium Salts at Rhodium and Iridium: A Chloride Additive Changes the Selectivity of C–H Activation;The Journal of Organic Chemistry;2021-12-30