Experimental and Computational Studies on the Acetate-Assisted C–H Activation of N-Aryl Imidazolium Salts at Rhodium and Iridium: A Chloride Additive Changes the Selectivity of C

Experimental and Computational Studies on the Acetate-Assisted C–H Activation of N-Aryl Imidazolium Salts at Rhodium and Iridium: A Chloride Additive Changes the Selectivity of C–H Activation

Published:2021-12-30 Issue:2 Volume:87 Page:1445-1456
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Tamosiunaite Neringa¹,Logie Lauren C.²,Neale Samuel E.²,Singh Kuldip¹,Davies David L.¹,Macgregor Stuart A.²^ORCID

Affiliation:

1. Department of Chemistry, University of Leicester, Leicester, LE1 7RH, U.K.

2. Institute of Chemical Sciences, Heriot-Watt University, Edinburgh, EH14 4AS, U.K.

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.joc.1c02756

Reference49 articles.

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2. Introduction: CH Activation

3. Mild metal-catalyzed C–H activation: examples and concepts

4. Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

5. Proton Abstraction Mechanism for the Palladium-Catalyzed Intramolecular Arylation

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