Manganese-Mediated C–H Bond Activation of Fluorinated Aromatics and the <i>ortho</i>-Fluorine Effect: Kinetic Analysis by <i>In Situ</i> Infrared Spectroscopic Analysis and Time-Resolved Methods-Reference-Cited by-同舟云学术

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Manganese-Mediated C–H Bond Activation of Fluorinated Aromatics and the ortho-Fluorine Effect: Kinetic Analysis by In Situ Infrared Spectroscopic Analysis and Time-Resolved Methods

Published:2022-01-11 Issue:2 Volume:12 Page:1532-1544
ISSN:2155-5435
Container-title:ACS Catalysis
language:en
Short-container-title:ACS Catal.

Author:

Hammarback L. Anders¹,Bishop Amy L.¹,Jordan Christina¹,Athavan Gayathri¹,Eastwood Jonathan B.¹,Burden Thomas J.¹,Bray Joshua T. W.¹,Clarke Francis¹,Robinson Alan²^ORCID,Krieger Jean-Philippe³,Whitwood Adrian¹^ORCID,Clark Ian P.⁴,Towrie Michael⁴,Lynam Jason M.¹^ORCID,Fairlamb Ian J. S.¹^ORCID

Affiliation:

1. Department of Chemistry, University of York, York YO10 5DD, United Kingdom

2. Syngenta Crop Protection AG, Schaffhauserstrasse, Basel 4332, Switzerland

3. Syngenta Crop Protection AG, Münchwilen, Breitenloh 5, Basel 4333, Switzerland

4. Central Laser Facility, STFC Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX, United Kingdom

Funder

Engineering and Physical Sciences Research Council

Syngenta International

Publisher

American Chemical Society (ACS)

Subject

Catalysis,General Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acscatal.1c05477

Reference56 articles.

1. Catalytic Borylation of SCF3-Functionalized Arenes by Rhodium(I) Boryl Complexes: Regioselective CH Activation at theortho-Position

2. Metal control of selectivity in acetate-assisted C–H bond activation: an experimental and computational study of heterocyclic, vinylic and phenylic C(sp2)–H bonds at Ir and Rh

3. A Highly Para-Selective Copper(II)-Catalyzed Direct Arylation of Aniline and Phenol Derivatives

4. Undirected, Homogeneous C–H Bond Functionalization: Challenges and Opportunities

5. A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

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4. Applications of Transition Metal-Catalyzed ortho-Fluorine-Directed C–H Functionalization of (Poly)fluoroarenes in Organic Synthesis;Chemical Reviews;2024-04-02

5. Unveiling Mechanistic Complexity in Manganese-Catalyzed C–H Bond Functionalization Using IR Spectroscopy Over 16 Orders of Magnitude in Time;Accounts of Chemical Research;2024-02-27

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