Structural diversity and spectral and thermal properties of the first alkaline earth metal tetracyanidoborates: [Mg(H2O)6][B(CN)4]2, [Mg(H2O)2][B(CN)4]2, [Mg(DMF)6][B(CN)4]2, [Ca(H2O)3][B(CN)4]2, and [Ca(H2O)2(CH3CN)][B(CN)4]2-Reference-Cited by-同舟云学术

Structural diversity and spectral and thermal properties of the first alkaline earth metal tetracyanidoborates: [Mg(H2O)6][B(CN)4]2, [Mg(H2O)2][B(CN)4]2, [Mg(DMF)6][B(CN)4]2, [Ca(H2O)3][B(CN)4]2, and [Ca(H2O)2(CH3CN)][B(CN)4]2

Published:2014 Issue:19 Volume:43 Page:7128-7138
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Nitschke Christian¹²³⁴,Köckerling Martin¹²³⁴,Bernhardt Eduard⁵⁶⁷,Küppers Torsten⁵⁶⁷,Willner Helge⁵⁶⁷

Affiliation:

1. Institut für Chemie

2. Anorganische Chemie/Festkörperchemie

3. Universität Rostock

4. D-18059 Rostock, Germany

5. FB C – Anorganische Chemie

6. Bergische Universität Wuppertal

7. D-42119 Wuppertal, Germany

Abstract

The syntheses, structures, and spectral and thermal properties of the first tetracyanidoborate salts coordinating weakly to solvated alkaline earth cations are discussed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT51945G

Reference44 articles.

1. Tetracyanoborate Salts M[B(CN)4] with M = Singly Charged Cations: Properties and Structures

2. Darstellung, spektroskopische Charakterisierung und Kristallstrukturen von Quecksilber(II)-bis(tetracyanoborat) Hg[B(CN)4]2 und Diquecksilber(I)-bis(tetracyanoborat) Hg2[B(CN)4]2Professor Dieter Naumann zum 60. Geburtstag gewidmet

3. The structures of Cu(i) and Ag(i) coordination polymers using the tricyanofluoroborate anion

4. Synthesis and characterization of the hexagonal prismatic cage {THF⊂[PhB(CN)3]6[Cp*Rh]6}6+

5. Synthesis of LiBC4N4, BC3N3, and Related C−N Compounds of Boron: New Precursors to Light Element Ceramics

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