Main group cyanides: from hydrogen cyanide to cyanido-complexes-Reference-Cited by-同舟云学术

Main group cyanides: from hydrogen cyanide to cyanido-complexes

Published:2022-09-21 Issue:1 Volume:43 Page:49-188
ISSN:0193-4929
Container-title:Reviews in Inorganic Chemistry
language:en
Short-container-title:

Author:

Schulz Axel¹^ORCID,Surkau Jonas¹^ORCID

Affiliation:

1. Chemie , Universität Rostock , Albert-Einstein-Straße 3a, 18059 Rostock , Mecklenburg-Vorpommern , Germany

Abstract

Abstract Homoleptic cyanide compounds exist of almost all main group elements. While the alkali metals and alkaline earth metals form cyanide salts, the cyanides of the lighter main group elements occur mainly as covalent compounds. This review gives an overview of the status quo of main group element cyanides and cyanido complexes. Information about syntheses are included as well as applications, special substance properties, bond lengths, spectroscopic characteristics and computations. Cyanide chemistry is presented mainly from the field of inorganic chemistry, but aspects of chemical biology and astrophysics are also discussed in relation to cyano compounds.

Publisher

Walter de Gruyter GmbH

Subject

Inorganic Chemistry

Link

https://www.degruyter.com/document/doi/10.1515/revic-2021-0044/pdf

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