Cyano(fluoro)borate and cyano(hydrido)borate ionic liquids: low-viscosity ionic media for electrochemical applications

Author:

Riefer Jarno1,Zapf Ludwig1,Sprenger Jan A. P.1,Wirthensohn Raphael1,Endres Sebastian2,Pöppler Ann-Christin2ORCID,Gutmann Marcus3,Meinel Lorenz3,Ignat'ev Nikolai V.14,Finze Maik1ORCID

Affiliation:

1. Julius-Maximilians-Universität Würzburg, Institut für Anorganische Chemie, Institut für nachhaltige Chemie & Katalyse mit Bor (ICB), Am Hubland, 97074 Würzburg, Germany

2. Julius-Maximilians-Universität Würzburg, Institut für Organische Chemie, Am Hubland, 97074 Würzburg, Germany

3. Julius-Maximilians-Universität Würzburg, Institut für Pharmazie und Lebensmittelchemie, Am Hubland, 97074 Würzburg, Germany

4. Consultant, Merck KGaA, Frankfurter Straße 250, 64293 Darmstadt, Germany

Abstract

Low-viscosity room-temperature ionic liquids (RTILs) and [BnPh3P]+ salts with the cyano(fluoro)borate anions [BF(CN)3] (MFB), [BF2(CN)2] (DFB), and [BF3(CN)] as well as the new mixed-substituted anion [BFH(CN)2] (FHB) are described.

Funder

Merck KGaA

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference94 articles.

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3. Ionic-liquid materials for the electrochemical challenges of the future

4. Electrochemical Aspects of Ionic Liquids , ed. H. Ohno , John Wiley & Sons, Inc. , Hoboken, New Jersey, USA , 2nd edn, 2011

5. Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2

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