Impact of thermal gas treatment on the surface modification of Li-rich Mn-based cathode materials for Li-ion batteries-Reference-Cited by-同舟云学术

Impact of thermal gas treatment on the surface modification of Li-rich Mn-based cathode materials for Li-ion batteries

Published:2023 Issue:17 Volume:4 Page:3746-3758
ISSN:2633-5409
Container-title:Materials Advances
language:en
Short-container-title:Mater. Adv.

Author:

Mellin Maximilian¹,Liang Zhili¹,Sclar Hadar²,Maiti Sandipan²,Píš Igor³^ORCID,Nappini Silvia³^ORCID,Magnano Elena³⁴^ORCID,Bondino Federica³^ORCID,Napal Ilargi³⁵,Winkler Robert¹,Hausbrand Réne¹,Hofmann Jan P.¹^ORCID,Alff Lambert¹^ORCID,Markovsky Boris²,Aurbach Doron²,Jaegermann Wolfram¹,Cherkashinin Gennady¹^ORCID

Affiliation:

1. Department of Materials and Earth Sciences, Technical University of Darmstadt, 64287 Darmstadt, Germany

2. Department of Chemistry, Bar-llan University, Ramat-Gan 5290002, Israel

3. IOM-CNR Istituto Officina dei Materiali, Strada Statale 14, km 163,5 in Area Science Park, 34149 Basovizza, Trieste, Italy

4. Department of Physics, University of Johannesburg, PO Box 524, Auckland Park, 2006, Johannesburg, South Africa

5. Università degli Studi di Trieste, Physics Department, P.le Europa 1, 34127 Trieste, Italy

Abstract

Thermal double gases SO2 and NH3 treatment of 0.33Li2MnO3·0.67LiNi0.4Co0.2Mn0.4O2 cathode materials leads to a partial reduction of the Co3+ and Mn4+ ions via electron transfer from SO2 to the transition metal sites and surface modification which acts as protective layer.

Funder

Deutsche Forschungsgemeinschaft

Diamond Light Source

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Chemistry (miscellaneous)

Link

http://pubs.rsc.org/en/content/articlepdf/2023/MA/D3MA00236E

Reference79 articles.

1. Lithium insertion into manganese spinels

2. Phospho‐olivines as Positive‐Electrode Materials for Rechargeable Lithium Batteries

3. Designing In-Situ-Formed Interphases Enables Highly Reversible Cobalt-Free LiNiO2 Cathode for Li-ion and Li-metal Batteries

4. Stabilized Behavior of LiNi0.85Co0.10Mn0.05O2 Cathode Materials Induced by Their Treatment with SO2

5. Boron doped Ni-rich LiNi0.85Co0.10Mn0.05O2 cathode materials studied by structural analysis, solid state NMR, computational modeling, and electrochemical performance

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