Voltage-dependent charge compensation mechanism and cathode electrolyte interface stability of the lithium-ion battery cathode materials LiCoO2 and LiNi1/3Mn1/3Co1/3O2 studied by photoelectron spectroscopy-Reference-Cited by-同舟云学术

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Voltage-dependent charge compensation mechanism and cathode electrolyte interface stability of the lithium-ion battery cathode materials LiCoO₂ and LiNi_1/3Mn_1/3Co_1/3O₂ studied by photoelectron spectroscopy

Published:2024 Issue:6 Volume:12 Page:3644-3658
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Mellin Maximilian¹^ORCID,Cherkashinin Gennady¹^ORCID,Mohseni Elham¹,Phillips Robert¹,Jaegermann Wolfram¹^ORCID,Hofmann Jan P.¹^ORCID

Affiliation:

1. Surface Science Laboratory, Department of Materials and Earth Sciences, Technical University of Darmstadt, Otto-Berndt-Strasse 3, 64287 Darmstadt, Germany

Abstract

Charge state dependent core level spectroscopy after in vacuo scratching reveals the electronic structure reasons for the high voltage limits of the relevant Li-ion battery cathode materials LiCoO2 (LCO) and LiNi1/3Mn1/3Co1/3O2 (NMC333).

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D3TA05981B

Reference62 articles.

1. Lithium Batteries and Cathode Materials

2. Layered Lithium Insertion Material of LiCo1/3Ni1/3Mn1/3O2for Lithium-Ion Batteries

3. Understanding the Anomalous Capacity of Li/Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] Cells Using In Situ X-Ray Diffraction and Electrochemical Studies

4. Electrochemical and Structural Properties of xLi2M‘O3·(1−x)LiMn0.5Ni0.5O2 Electrodes for Lithium Batteries (M‘ = Ti, Mn, Zr; 0 ≤ x ⩽ 0.3)

5. Recent progress in high-voltage lithium ion batteries

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