Ring-opening of cyclic ethers by aluminum hydridotriphenylborate-Reference-Cited by-同舟云学术

Ring-opening of cyclic ethers by aluminum hydridotriphenylborate

Published:2017 Issue:24 Volume:53 Page:3493-3496
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Mukherjee Debabrata¹²³⁴,Osseili Hassan¹²³⁴,Truong Khai-Nghi¹²³⁴,Spaniol Thomas P.¹²³⁴,Okuda Jun¹²³⁴^ORCID

Affiliation:

1. Institute of Inorganic Chemistry

2. RWTH Aachen University

3. 52056 Aachen

4. Germany

Abstract

Ring-opening of THF or THP in the presence of pinacolborane can be catalyzed by a molecular aluminum hydride catalyst [(L)AlH₂]₂ (L = Me₃TACD)/BPh₃ and involves an isolable intermediate [(L)AlH][HBPh₃].

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC01159H

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